Mandel Scientific Company Inc.

Risk Phrases

N/A	No Known Risk
R 1	Explosive when dry.
R 2	Risk of explosion by shock, friction, fire or other sources of ignition.
R 3	Extreme risk of explosion by shock, friction, fire or other sources ignition.
R 4	Forms very sensitive explosive metallic compounds.
R 5	Heating may cause an explosion
R 6	Explosive with or without contact with air.
R 7	Combustible.
R 8	Contact with combustible material may cause fire.
R 9	Explosive when mixed with combustible material.
R 10	Flammable.
R 11	Highly flammable.
R 12	Extremely flammable.
R 14	Reacts violently with water.
R 15	Contact with water liberates extremely flammable gases.
R 16	Explosive when mixed with oxidizing substances.
R 17	Spontaneously flammable in air.
R 18	In use, may form flammable/explosive vapor-air mixture.
R 19	May form explosive peroxides.
R 20	Harmful by inhalation.
R 21	Harmful in contact with skin.
R 22	Harmful if swallowed.
R 23	Toxic by inhalation.
R 24	Toxic in contact with skin.
R 25	Toxic if swallowed.
R 26	Very toxic by inhalation.
R 27	Very toxic in contact with skin.
R 28	Very toxic if swallowed.
R 29	Contact with water liberates toxic gas.
R 30	Can become highly flammable in use.
R 31	Contact with acids liberates toxic gas.
R 32	Contact with acids liberates very toxic gas.
R 33	Danger of cumulative effects.
R 34	Corrosive.
R 35	Causes severe burns.
R 36	Irritating to eyes.
R 37	Irritating to respiratory system.
R 38	Irritating to skin.
R 39	Danger of very serious irreversible effects.
R 40	Limited evidence of a carcinogenic effect.
R 41	Risk of serious damage to eyes.
R 42	May cause sensitization by inhalation.
R 43	May cause sensitization by skin contact.
R 44	Risk of explosion if heated under confinement.
R 45	Suspected Carcinogen.
R 46	May cause heritable genetic damage.
R 48	Danger of serious damage to health by prolonged exposure.
R 49	May cause cancer by inhalation.
R 50	Very toxic to aquatic organisms.
R 51	Toxic to aquatic organisms.
R 52	Harmful to aquatic organisms.
R 53	May cause long-term adverse effects in the aquatic environment.
R 54	Toxic to flora.
R 55	Toxic to fauna.
R 56	Toxic to soil organisms.
R 57	Toxic to bees.
R 58	May cause long-term adverse effects in the environment.
R 59	Dangerous for the ozone layer.
R 60	May impair fertility.
R 61	May cause harm to the unborn child.
R 62	Possible risk of impaired fertility.
R 63	Possible risk of harm to the unborn child.
R 64	May cause harm to breast-fed babies.
R 65	Harmful: may cause lung damage if swallowed.
R 66	Repeated exposure may cause skin dryness or cracking.
R 67	Vapors may cause drowsiness and dizziness.
R 68	Possible risk of irreversible effects.

Combination Risk Phrases
R 14/15	Reacts violently with water liberating extremely flammable gases.
R 15/29	Contact with water liberates toxic, extremely flammable gas.
R 20/21	Harmful by inhalation and in contact with skin.
R 20/22	Harmful by inhalation and if swallowed.
R 21/22	Harmful in contact with skin and if swallowed.
R 20/21/22	Harmful by inhalation, in contact with skin and if swallowed.
R 23/24	Toxic by inhalation and in contact with skin.
R 23/25	Toxic by inhalation and if swallowed.
R 23/24/25	Toxic by inhalation, in contact with skin and if swallowed.
R 24/25	Toxic in contact with skin and if swallowed.
R 26/27	Very toxic by inhalation and in contact with skin.
R 26/28	Very toxic by inhalation and if swallowed.
R 26/27/28	Very toxic by inhalation, in contact with skin and if swallowed.
R 27/28	Very toxic in contact with skin and if swallowed.
R 36/37	Irritating to eyes and respiratory system.
R 36/38	Irritating to eyes and skin.
R 36/37/38	Irritating to eyes, respiratory system and skin.
R 37/38	Irritating to respiratory system and skin.
R 39/23	Toxic: danger of very serious irreversible effects through inhalation.
R 39/24	Toxic: danger of very serious irreversible effects in contact with skin.
R 39/25	Toxic: danger of very serious irreversible effects if swallowed.
R 39/23/24	Toxic: danger of very serious irreversible effects through inhalation and in contact with skin.
R 39/23/25	Toxic: danger of very serious irreversible effects through inhalation and if swallowed.
R 39/24/25	Toxic: danger of very serious irreversible effects in contact with skin and if swallowed.
R 39/23/24/25	Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
R 39/26	Very toxic: danger of very serious irreversible effects through inhalation.
R 39/27	Very toxic: danger of very serious irreversible effects in contact with skin.
R 39/28	Very toxic: danger of very serious irreversible effects if swallowed.
R 39/26/27	Very toxic: danger of very serious irreversible effects through inhalation and in contact with skin.
R 39/26/28	Very toxic: danger of very serious irreversible effects through inhalation and if swallowed.
R 39/27/28	Very toxic: danger of very serious irreversible effects in contact with skin and if swallowed.
R 39/26/27/28	Very toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
R 42/43	May cause sensitization by inhalation and skin contact.
R 48/20	Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R 48/21	Harmful: danger of serious damage to health by prolonged exposure in contact with skin.
R 48/22	Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R 48/20/21	Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
R 48/20/22	Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
R 48/21/22	Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R 48/20/21/22	Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
R 48/23	Toxic: danger of serious damage to health by prolonged exposure through inhalation.
R 48/24	Toxic: danger of serious damage to health by prolonged exposure in contact with skin.
R 48/25	Toxic: danger of serious damage to health by prolonged exposure if swallowed.
R 48/23/24	Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
R 48/23/25	Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
R 48/24/25	Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R 48/23/24/25	Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
R 50/53	Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 51/53	Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 52/53	Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 68/20	Harmful: possible risk of irreversible effects through inhalation.
R 68/20/21	Harmful: possible risk of irreversible effects through inhalation, in contact with skin.
R 68/20/21/22	Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.
R 68/20/22	Harmful: possible risk of irreversible effects through inhalation and if swallowed.
R 68/21	Harmful: possible risk of irreversible effects in contact with skin.
R 68/21/22	Harmful: possible risk of irreversible effects in contact with skin and if swallowed.
R 68/22	Harmful: possible risk of irreversible effects if swallowed.

Safety Phrases
S 1	Keep locked up.
S 2	Keep out of reach of children.
S 3	Keep in a cool place.
S 4	Keep away from living quarters.
S 5	Keep contents under (appropriate liquid to be specified by the manufacturer).
S 6	Keep under (inert gas to be specified by the manufacturer).
S 7	Keep container tightly closed.
S 8	Keep container dry.
S 9	Keep container in a well ventilated place.
S 12	Do not keep the container sealed.
S 13	Keep away from food, drink and animal feeding stuffs.
S 14	Keep away from (incompatible materials to be indicated by the manufacturer).
S 15	Keep away from heat.
S 16	Keep away from sources of ignition-No smoking.
S 17	Keep away from combustible material.
S 18	Handle and open container with care.
S 20	When using do not eat or drink.
S 21	When using do not smoke.
S 22	Do not breathe dust.
S 23	Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer).
S 24	Avoid contact with skin.
S 25	Avoid contact with eyes.
S 26	In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 27	Take off immediately all contaminated clothing.
S 28	contact with skin, wash immediately with plenty of (to be specified)
S 29	Do not empty into drains.
S 30	Never add water to this product.
S 33	Take precautionary measures against static discharges.
S 35	This material and its container must be disposed of in a safe way.
S 36	Wear suitable protective clothing.
S 37	Wear suitable gloves.
S 38	In case of insufficient ventilation, wear suitable respiratory equipment.
S 39	Wear eye/face protection.
S 40	To clean the floor and all objects contaminated by this material, use (to be specified by the manufacturer).
S 41	In case of fire and/or explosion do not breathe fumes.
S 42	During fumigation/spraying wear suitable respiratory equipment. (appropriate wording to be specified).
S 43	In case of fire, use (indicate in the space the precise type of fire-fighting equipment. If water increases the risk, add - Never use water).
S 44	If you feel unwell, seek medical advice (show the label where possible).
S 45	In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S 46	If swallowed seek medical advice immediately and show this container or label.
S 47	Keep at temperature not exceeding _°C (to be specified by the manufacturer).
S 48	Keep wetted with (appropriate material to be specified by the manufacturer).
S 49	Keep only in the original container.
S 50	Do not mix with (to be specified by the manufacturer).
S 51	Use only in well ventilated areas.
S 52	Not recommended for interior use on large surface areas.
S 53	Avoid exposure - obtain special instructions before use.
S 56	Dispose of the material and its container to hazardous or special waste collection point.
S 57	Use appropriate containment to avoid environmental contamination.
S 59	Refer to manufacturer/supplier for information on recovery/recycling.
S 60	This material and/or its container must be disposed of as a hazardous waste.
S 61	Avoid release to the environment. Refer to special instructions/safety data sheet.
S 62	If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S 63	In case of accident by inhalation, remove casualty to fresh air and keep at rest.
S 64	If swallowed, rinse mouth with water (only if the person is conscious).

Combination Safety Phrases
S 1/2	Keep locked up and out of reach of children.
S 3/9/14	Keep in a cool, well ventilated place away from__ (incompatible materials to be indicated by the manufacturer).
S 3/9/14/49	Keep only in the original container in a cool well-ventilated place away from (incompatible materials to be indicated by the manufacturer).
S 3/9/49	Keep only in the original container in a cool well-ventilated place.
S 3/14	Keep in a cool place away from (incompatible materials to be specified by the manufacturer).
S 7/8	Keep container tightly closed and dry.
S 7/9	Keep container tightly closed and in well-ventilated place.
S 20/21	When using do not eat, drink or smoke.
S 24/25	Avoid contact with skin and eyes.
S 36/37	Wear suitable protective clothing and gloves.
S 36/39	Wear suitable protective clothing and eye/face protection.
S 37/39	Wear suitable gloves and eye/face protection.
S 36/37/39	Wear suitable protective clothing, gloves and eye/face protection.
S 47/49	Keep only in the original container at temperature not exceeding _°C (to be specified by the manufacturer).